Volibear's Skill Max Order: W → Q → E
Or: E → W → Q
Matchup Tip: Quinn's E can cancel Voli's Q anytime during his animation, even if the auto attack animation goes off, and his stun and damage will not go through. His Q gets reset after this, but your E slow + W passive movespeed makes you faster, so when he uses Q, use E on him when he gets into melee range of you to escape.
If you struggle in this matchup, berserker boots rush are really good to grant you MS to easily avoid his engages, especially post 6 when he has R.
Level 1: Voli starts E, so Quinn Cheese level 1 from the bush and then run forward to walk out of his following Sky Splitter lightning bolt. His E is 3 seconds longer than your E, so make sure to E again the second it's off cooldown level 1 to go for a free trade.
Level 2: Voli will have Q, but your E can cancel it. Be more careful about E usage because a good Voli will use his Q after your E is down to get a stun off on you. I typically like saving my E to counter his Q engage in this matchup.
Level 3: Voli can't do much before level 6. Save E to cancel his Q engage, and then use your range advantage to bully him every other time in lane. You are faster than him and directly counter him if you follow this.
Level 6: Do not use your E on Voli when he uses his R because his R is immune to CC, so it is best to let him land and then use your E on him after he lands.
First, to beat Volibear, you will start off with your tier 2 berzerker boots FIRST.
Legit do not buy long swords, you will be rushing boots first.
So, in an ideal world, you will stay in lane until 1100g, where you will buy the boots in full.
If you back early don't worry, just get tier 1 boots/dagger and pots/pink ward. Why early boots? Because volibear is a champion where movement speed counters his entire kit.
When Voli tries to engage on you (he will press Q and start running on the ground and make a sound, so you will know when he presses his Q), Vault him whenever BEFORE he comes at you.
Your vault CANCELS his Q stun and pushes you to safety.
So, how to play this lane is to legit just shove him in and poke him with 3 autos whenever PTA is available, use Q and autos along with passive whenever possible, but NEVER USE YOUR E! The only time you use your E in this matchup is to cancel his Q and his Q only (his Q is when he runs at you to stun you).
Do not ever vault his R cuz he's unstoppable, so post 6 when he ults, wait for him to land and press Q, then E the Q and auto to consume harrier proc, then run away.
The only thing to watch out for is his W, voli will like to use W to summon his circle to slow you before engaging, so try to dodge it if you can with your fast speed.
Make sure to constantly apply pressure and auto him because this matchup is literally volibear's toughest matchup top lane.
You hard counter him, so play with confience.